That type of master vol works by forcing the PI to clip at progressively lower levels. I'm not sure that your test proves that the PI is clipping; rather it is proving that your master vol is working, by forcing the PI to clip before the power tubes.I know (well, I'm almost certain) it was the PI clipping because I also instaled a post PI MV by connecting a large cap and a pot between both PI outs (that cancels 180 degree out of phase signal, for those who might not know). So with little signail to the power tubes I could tell that the PI was clipping.
With any properly implemented design, the power tubes must clip before the PI, which, given suitable control settings, must clip before the preamp.
Otherwise the amp could never produce full power.
Pete